By Gregory J. Kubas
Based on R.H. Crabtree, steel Dihydrogen and -Bond Complexes is defined as `the definitive account of twentieth-century paintings within the sector of sigma complexation'. It covers not just Kubas' discovery of dihydrogen coordination and the examine of its constitution and normal houses but additionally discusses either the theoretical ideals and experimental result of bonding and activation of dihydrogen on steel facilities and the coordination and activation of C--H, B--H, X--H, and X--Y bonds, giving an summary of `one of the most popular parts in chemistry'.
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Chem. Soc. ; Lluch, J. M. J. Am. Chem. Soc. ; Otero, A. Coord. Chem. Rev.
Ashworth, T. ; Singleton, E. J. Chem. , Chem. Commun. 1976, 705. 30. Gusev, D. ; Vymenits, A. ; Bakhmutov, V. I. Inorg. Chim. Acta 1991, 179, 195. 31. ; Kubas, G. ; Van Der Sluys, L. , unpublished results 1993. 32. Sweany, R. L. J. Am. Chem. Soc. 1985, 107, 2374. 33. Upmacis, R. ; Gadd, G. ; Simpson, M. ; Turner, J. ; Simpson, A. F. J. Chem. , Chem. Commun. 1985, 27; Church, S. ; Shaffner, K. J. Chem. , Chem. Commun. 1985, 30. 34. Crabtree, R. ; Lavin, M. J. Chem. , Chem. Commun. 1985, 1661. 35.
It is remarkable that only two documented examples of homogeneous catalytic activation of by metal complexes were reported prior to 1953 when Halpern began his studies and heterogeneous hydrogenation predominated. The first dates back to 1938 when Calvin3 reported that salts such as acetate catalyzed reduction by of substrates such as and quinone under mild homogeneous conditions. It is surprising that this discovery was not appreciated or followed up for 15 years, despite the fact that it was only heterogeneous activation of that had been known up to that time.