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Subsequent rearrangement of the vinyl products was shown. The kinetically con29 30 31 32 34 35 E. C. Ashby, L. C. Chao, and J. Laemmle, J. Org. , 1974, 39, 3258. A. Meyer and G. S. Chem. , 1974, 787. A. I. Meyers and M. E. Ford, Tetrahedron Letters, 1974, 1341. C. Foucquey, J. Jacques, L. Angiolini, and M. Tramontini, Tetrahedron, 1974, 30, 2801; A. Gaset and A. Lattes, J. , 1974, 71, 1. M. Gocmen and G. Soussan, J. , 1974, 80, 303. B. S. Chem. , 1974, 750. (a) M. Dagonneau and J. , 1974, 30, 415; (c) M.
Schmidt and G. , 1974, 2561 ;C. Bacquet, J. Villieras, and J. F. Normant, Compt. , 1974,278, C, 929; H. Taguchi, M. Yamamoto, and H. Nozaki, J. Amer. Chem. ,1974,96, 3010; T. Hiyama, S. Takehara, K. Kitatani, and H. Nozaki, Tetrahedron Letters, 1974, 3295; M. Braun and D. Seebach, Angew. Chem. Internat. Edn, 1974, 13, 277. ll* W. T. Ford and M. Newcomb, J. Amer. Chem. ,1974,96, 309. l l DJ. E. Baldwin, G. A. Hofle, and 0. W. Lever, J. Amer. Chem. ,1974,96, 7125. 95 96 2 Group II: The Alkaline Earths and Zinc and its Congeners BY J.
C. B. Rose and S. K. Taylor, J. Org. , 1974, 39, 578. G. Courtois and L. Miginiac, J. , 1974, 69, 1. Y. Kiso, K. Tamao, N. Miyake, K. Yamamoto, and M. Kumada, Tetrahedron Letters, 1974, 3. Y. Ohbe, M. Takagi, and T. Matsuda, Tetrahedron, 1974, 30, 2669. M . Schlosser, Angew. Chem. Internat. Edn, 1974, 13, 701. R. Zerger and G. Stucky, J. , 1974, 80, 7 . 22 Organometallic Chemistry The metallation of acidic hydrocarbons, such as f l ~ o r e n e , ~ li~~, ~ b d e n e , ~cyclol~*b pentadiene,Sla PhC=CH,5la Ph&H,51b and PhzCHz 51b by Ph3CCaC15la and by PhzCa51b in THF and other ethereal media were reported.