By Y. G. Medvedevskikh, Artur Valente, Robert A. Howell, G. E. Zaikov
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Extra resources for Organic and Physical Chemistry Using Chemical Kinetics: Prospects and Developments
Sample text
Calculated on this basis value δ of coal increases droningly with increasing the content of carbon from 70 % till 87 % and in a case of more metamorphized coal is sharply decreased again. Data concerning to the extraction of Greta coal are evidence of maximal yield of extract (more than 20 %) under it treatment with ethylendiamine and dimethylformamide (δ – 11,5), however, authors admit a fact that this is a consequence of specific interactions, since in alcohol from the δ of the same order the yield of the extract is only 1 – 2 %.
G. Medvedevskikh, et al. pp. 35-49 © 2007 Nova Science Publishers, Inc. Chapter 3 GENERALIZATION OF DATA CONCERNING TO THE COAL SWELLING IN ORGANIC SOLVENTS AND THEIR EXTRACTION USING THE LINEAR MULTIPARAMETRIC EQUATIONS L. I. Bazylyak*1, D. V. Bryk*2, R. G. Makitra2, R. Ye. Prystansky1 and G. E. Zaikov*3 1 Physical Chemistry of Combustible Minerals Department; L. M. Lytvynenko Institute of Physical–Organic Chemistry and Carbon Chemistry; National Academy of Sciences of Ukraine 2 Institute of Geology and Geochemistry of Combustible Minerals; National Academy of Sciences of Ukraine 3 N.
The data concerning to W taken from [9] and calculated on their basis swelling values in moles Q and lgQ are presented in Table 2; the generalization of these data in accordance with the sixth parameter equation (7) leads to higher degree of relationship R = 0,909, and the exclusion from the consideration of one solvent (butylamine) gives the possibility to obtain the equation with satisfactory degree of relationship R = 0,974; an additional exclusion of dimethylformamide gives the equation (11) with R = 0,991.