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A classical article on it by Conway and Gileadi exists. 40 Bockris, Gileadi, and Stoner 127 maintained an electrode at constant potential while observing the current produced by introducing an organic substance into solution. In the un dissociated case, the current is calculable. It is less than that in which the molecule is dissociating and injecting charge into the electrode. Few methods exist for identifying radicals on surfaces. The first was devised by Armstrong and Butler,128 who determined the amount of hydrogen on platinum.
Symp. , 1959, p. 294 (1961). 60. R. D. Armstrong, 1. Electroanal. Chem. 20,168 (1968). 61. A. N. Frumkin, referred to on p. 265 of L. Antropov, Theoretical Electrochemistry, Mir, Moscow (1972). 62. L. Antropov, Theoretical Electrochemistry, Mir, Moscow (1972). 63. J. O'M. Bockris, Energy Conversion 10,41 (1970). 64. J. O'M. Bockris, E. Gileadi, and G. Stoner, 1. Electrochem. Soc. 113, 585 (1966). 65. J. O'M. Bockris, 1. Electroanal. Chem. 34, 1,201 (1972). 66. A. N. Frumkin and A. Gorodetskaya, Z.
E. A. Blomgren, J. O'M. Bockris, and C. Jesch, J. Phys. Chem. 75, 2000 (1961). 115. B. B. Damaskin and A. N. Frumkin, Reactions of Molecules at Electrodes, (N. S. ), p. I, Wiley (Interscience), London (1971). 116. E. A. Blomgren and J. O'M. Bockris, J. Phys. Chem. 63,1475 (1959). 117. J. O'M. Bockris, M. Green, and D. A. J. Swinkels, J. Electrochem. Soc. 111, 743 (1964); J. O'M. Bockris and D. A. J. Swinkels, J. Electrochem. Soc. 111, 736 (1964). 118. B. B. Damaskin, J. Electroanal. Chem. 23, 431 (1969).