By Boschke F.L.
Content material: Chemically caused dynamic nuclear polarization, by way of H. Fischer. -- Critique of the movement of aromaticity, via J.-F. Labarre and F. Crasnier
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Commun. 1969, 1345. 1971. Baldwin, J. , Brown, J. : J. Am. Chem. Soc. 91, 3647 (1969). -- Erickson, W. , Hackler, R. , Scott, R. : Chem. Commun. 1970, 576. - Brown, J. : J . A m . Chem. Soc. 93, 788 (1971). : Tetrahedron Letters 1971, 63. : Bull. Chem. Soe. Japan 43, 3638 (1970). J. Am. Chem. Soc. 92, 7474 (1970). -- Tetrahedron Letters 1970, 3723. , Neumann, W. : Angew. 1971. , Roth, H. : J. Am. Chem. Soc. 92, 2573 (1970). Roth, H. 1971. , Trozzolo, A. : J. Am. Chem. Soc. 92, 1774 (1970). , Trozzolo, A.
93, 788 (1971). : Tetrahedron Letters 1971, 63. : Bull. Chem. Soe. Japan 43, 3638 (1970). J. Am. Chem. Soc. 92, 7474 (1970). -- Tetrahedron Letters 1970, 3723. , Neumann, W. : Angew. 1971. , Roth, H. : J. Am. Chem. Soc. 92, 2573 (1970). Roth, H. 1971. , Trozzolo, A. : J. Am. Chem. Soc. 92, 1774 (1970). , Trozzolo, A. 1971. Hollander, J. 1971. , Mennit L P. : Unpublished: Janzen, E. : Acc. Chem. Res. 4, 31 (1971). Lebin, Ya. , Iljasov, A. , Pobedinskij, D. , Samupov, Yu. , Sauda, I. , Goldfars, E.
So far, only a limited amount of information is available i e,~f,l~ ,39,48,49) and no thorough theoretical study has been reported. Preliminary results indicate, however, that the low-field polarizations are explainable in terms of suitable extensions o f the high-field theories of Sect. 33,39,48,49). Future investigations have also to establish the potentialities of CIDNP in the detection o f biradical intermediates. Recently Closs 6k) reported CIDNP effects for reactions where such intermediates are present and outlined the pertinent theory which indicates severe restrictions.