By Allen J. Bard, Israel Rubinstein
For greater than 3 many years the Electroanalytical Chemistry series has introduced the main in-depth and significant examine relating to concerns in electrochemistry. Volume 22 continues this gold-standard with useful experiences of contemporary purposes, in addition to cutting edge contributions from the world over revered specialists―highlighting the emergence of recent applied sciences and developments within the box. earlier volumes within the sequence have been “highly prompt” through the magazine of the yankee Chemical Society and thought of “essential” via the Journal of reliable kingdom Electrochemistry, and this quantity keeps with a suite of cutting-edge advances and reviews of the top quality.
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Example text
Furthermore, the potential at which E m approaches zero is close to the reported pzc* (Ϫ4 mV for Au in 1 mM NaF [95]). Figure 12 shows that the gold nanotubule membranes can function as electronically switchable ion exchange membranes. However, it would seem that this would only be possible if the electrolyte contained only nonadsorbing anions such as FϪ. If a chemisorbing anion (such as ClϪ or BrϪ ) [90,96] were present, it would adsorb at positive applied potentials yielding a cation-permselective membrane.
0), a plot of E m versus log(a h /a l ) would be linear, with an intercept of 0 and a slope of 59 mV (dashed line, Fig. 11). A concentration cell was assembled in which a gold nanotubule mem© 1999 by Marcel Dekker, Inc. FIG. 11. E m values obtained for membranes prepared for the indicated plating times. 1 mM KCl. 1 mM KCl to 1 M KCl. The E m values were measured by using two Ag/AgCl (KCl saturated) electrodes placed in each half-cell through agar salt-bridges. The dashed line is for ideal cationpermselective behavior.
Furthermore, this effect is reproducible and reversible. , 1 mM), the voltammetric wave immediately assumes the reversible appearance characteristic of the low electrolyte concentration solution (Fig. 10). Furthermore, we have observed this effect for NEEs prepared from both polycarbonate and polyester membranes, for NEEs prepared from membranes with and without the PVP that is used to improve membrane wettability, and for NEEs with low densities of elec- FIG. 10. Cyclic voltammograms illustrating the effect of supporting electrolyte concentration at a 10NEE.