By Roger Alberto (auth.), W. Krause (eds.)
R. Alberto: New Organometallic Technetium Complexes for Radiopharmaceutical Imaging.-
I. Santos, A. Paulo, J.D.G. Correia: Re and Tc Complexes Anchored through Phosphines and Scorpionates for Radiopharmaceutical Applications.-
A. Boschi, A. Duatti, L.Uccelli: improvement of Technetium-99m and Rhenium-188 Radiopharmaceuticals Containing a Terminal Metal-Nitrido a number of Bond for prognosis and Therapy.-
S. Liu: HYNIC Derivatives as Bifunctional Coupling brokers for 99mTc-Labeling of Small Biomolecules.-.
V. Sharma, D. Piwnica-Worms: tracking Multidrug Resistance P-glycoprotein (MDR1 Pgp) Drug delivery job with SPECT and puppy Radiopharmaceuticals.-
W.P. Li, L.A. Meyer, C.J. Anderson: Radiopharmceuticals for puppy Imaging of Somatostatin Receptor optimistic Tumors.-
S. Liu, S.P. Robinson, D.S. Edwards: Radiolabeled Integrin av?3 Antagonists as Radiopharmaceuticals for Tumor Radiotherapy.
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Extra info for Contrast Agents III: Radiopharmaceuticals – From Diagnostics to Therapeutics
Example text
49 50 50 50 53 55 57 57 59 63 63 64 66 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70 71 71 74 75 75 Concluding Remarks and Perspectives . . . . . . . . . . 79 . . . . . . . . . . . . . . . . .
At the macroscopic and at the noncarrier added level, the only complexes identified were [99/99mTcN(P1O)2] (10, 10a) [26]. Biodistribution studies of 10a in rats have shown some transient heart uptake, but a significant amount of activity was also retained into the lungs [26]. As depicted in Scheme 2, the “[ReO(P1O)]2+” moiety can accommodate aminodithiolate ligands (11), other tridentate ligands containing a central amine group (12), model peptide fragments (13) and Schiff bases (14) [30–34]. These 3+2 compounds, 11–14, are closed-shell 18-electron oxorhenium species, adopting a distorted octahedral geometry in the solid state or in solution, as demonstrated by classical spectroscopical methods, including multinuclear NMR.
70 71 71 74 75 75 Concluding Remarks and Perspectives . . . . . . . . . . 79 . . . . . . . . . . . . . . . . . . . 80 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47 Abstract This review presents a comprehensive overview of the most significant developments in the chemistry of technetium and rhenium complexes anchored by heterofunctionalized phosphines and by hard and soft scorpionates.